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Solvolysis and rearrangement of aryl vinyl compounds in pyridine hydrochloride

✍ Scribed by David W. Johnson; George Phillipou

Publisher
Elsevier Science
Year
1979
Tongue
French
Weight
95 KB
Volume
20
Category
Article
ISSN
0040-4039

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✦ Synopsis

Anisyl substituted stilbenes undergo concommitant thermal rearrangement and loss of a halogen atom with dealkylation in pyridine hydrochloride.

πŸ“œ SIMILAR VOLUMES

Photochemical arylation by oxime esters
Photochemical arylation by oxime esters in benzene and pyridine: simple synthesis of biaryl compounds
✍ Masato Hasebe; Koichi Kogawa; Takashi Tsuchiya πŸ“‚ Article πŸ“… 1984 πŸ› Elsevier Science 🌐 French βš– 189 KB

Aryl radicals are generated by various ways among which thermal decomposition of arenecarbonyl peroxides, 1 arenediazonium salts, 2 acylarylnitrosoamines, 3 and aryl triazenes 4 which are used as efficient precursors for radical reactions. Although they may be useful compounds to generate aryl