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Solvolyse von bicyclo[3.1.0]hex - 2-en-3-yltriflat

✍ Scribed by Wolfgang Eymann; Michael Hanack


Publisher
Elsevier Science
Year
1976
Tongue
French
Weight
111 KB
Volume
17
Category
Article
ISSN
0040-4039

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πŸ“œ SIMILAR VOLUMES


Generation and reactivity of sterically
✍ Richard F. Salinaro; Jerome A. Berson πŸ“‚ Article πŸ“… 1982 πŸ› Elsevier Science 🌐 French βš– 224 KB

Z-t-Butylbicyclo[3.1.O]hex-1-ene dimerizes primarily by a [o + IT] way, whereas 2,5-di-t-butylbicyclo[3.l.O]hex-1-ene undergoes an unusual hydrogen shift reaction to 1,3-di-t-butyl-2-methylcyclopentadiene. The presence of bulky substituents on or near the strained double bond of a bicyclo[3.l.O]hex-