✦ LIBER ✦
Solvolyse von 2-(α-Chlorbenzyl)-chinuclidin. Zur Kenntnis der Heterocinchonin-Umlagerung. Chinuclidin-Reihe, 7. Mitteilung
✍ Scribed by V. Braschler; C. A. Grob; A. Kaiser
- Publisher
- John Wiley and Sons
- Year
- 1963
- Tongue
- German
- Weight
- 967 KB
- Volume
- 46
- Category
- Article
- ISSN
- 0018-019X
No coin nor oath required. For personal study only.
✦ Synopsis
Abstract
Reaction rate and hydrolysis products of 2‐(α‐chlorobenzyl)‐quinuclidine (13b) provide no evidence for the participation of the quinuclidine nitrogen in the ionisation step of this unusual β‐haloamine. Furthermore, no product derived from a «hetero‐cinchonine rearrangement» was isolated.