Kate constants of change transfer reactions ~ZCT, involving C&g alkanes and cycloalkanes, have been determined in an ion cyclotron resonance mass spectrometer. The rate constants are significantly lower than the corresponding rate constants for collision when the reaction is less than about 0.5 eV e
Solvent–iodine atom charge transfer absorption in liquid alkanes and cycloalkanes
✍ Scribed by Logan, S. R.; Bonneau, R.; Joussot-Dubien, J.; de Violet, P. Fornier
- Book ID
- 120260949
- Publisher
- The Royal Society of Chemistry
- Year
- 1975
- Weight
- 640 KB
- Volume
- 71
- Category
- Article
- ISSN
- 0300-9589
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📜 SIMILAR VOLUMES
UV absorption spectrum ofchlorine atoms has been measured in several halogenated solvents following 355 nm laser flash photolysis of molecular chlorine. A linear correlation between band maxima and solvent ionization potential indicates the tran-. sitions are chlorine atom/solvent change-transfer ab
Two bands have been rcsolvcd tn the lrcluj~-pb~~~ spcctn of transrcnt complcxo bctwccn I atoms and ~WC alkyl ioddes. lonkation potential dcpcndcncc and similarrty to compamblu vapor-phase sysfcms indiwtc the clwrgc-transfer miturc of both bands.