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Solvent Self-Diffusion in Glassy Polymer-Solvent Systems

✍ Scribed by Vrentas, J. S.; Vrentas, C. M.

Book ID
126167347
Publisher
American Chemical Society
Year
1994
Tongue
English
Weight
805 KB
Volume
27
Category
Article
ISSN
0024-9297

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πŸ“œ SIMILAR VOLUMES

Self-diffusion in polymer-solvent-solven
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## Abstract The ternary self‐diffusion data of Ferguson and von Meerwall are analyzed using a generalized form of the free‐volume theory of diffusion proposed by Vrentas and Duda. It is shown that the predicative capabilities of this form of the theory are satisfactory and comparable to those of th

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In this article, a mathematical model is proposed for predicting solvent self-diffusion coefficients in amorphous glassy polymers based on free volume theory. The basis of this new model involves consideration of the plasticization effects induced by small molecular solvents to correctly estimate th