Solvent self-diffusion in crosslinked polymers
β Scribed by J. S. Vrentas; C. M. Vrentas
- Publisher
- John Wiley and Sons
- Year
- 1991
- Tongue
- English
- Weight
- 512 KB
- Volume
- 42
- Category
- Article
- ISSN
- 0021-8995
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π SIMILAR VOLUMES
In this article, a mathematical model is proposed for predicting solvent self-diffusion coefficients in amorphous glassy polymers based on free volume theory. The basis of this new model involves consideration of the plasticization effects induced by small molecular solvents to correctly estimate th
## Abstract The problem of the delayed crosslinking arising due to the diffusion of a crosslinker molecule from a vector particle within a thermoset polymer matrix is discussed. The crosslinker molecules, initially embedded in the vector particles, diffuse from the particle to the polymer matrix an