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Solvent perturbs the reactivity of tert-butylcarbene

✍ Scribed by Rebecca T. Ruck; Maltland Jones Jr.

Publisher
Elsevier Science
Year
1998
Tongue
French
Weight
245 KB
Volume
39
Category
Article
ISSN
0040-4039

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✦ Synopsis

Two different sources of Ml-butybarbene are used to generate thii reactive intermediate in a variety of solvents. Two products, 1 ,ldimethylcyclopmpane and P-methyl-Pbutens are formed. Solvents able to form an ylid or complex wfth the carbine strongly favor the alkene product.

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