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Solvent-Mediated Ion Exchange and Structural Transformations of Cluster-Based Coordination Polymers

✍ Scribed by Jian-Jun Zhang; Yue Zhao; Sergio Aarón Gamboa; Miguel Muñoz; Abdessadek Lachgar


Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
822 KB
Volume
2008
Category
Article
ISSN
1434-1948

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## Abstract Two prototypical carbido anionic clusters, the prismatic [Rh~6~C(CO)~15~]^2–^ and the octahedral [Ru~6~C(CO)~16~]^2–^, can add two electrophilic Ag–NCMe^+^ fragments, which were exploited to condense the clusters with bifunctional heterocyclic ligands, such as pyrazine (pyz) or 4,4′‐bip