𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Solvent-Ligated Manganese(II) Complexes for the Homopolymerization of Isobutene and the Copolymerization of Isobutene and Isoprene

✍ Scribed by Mario Vierle; Yanmei Zhang; Ana M. Santos; Klaus Köhler; Carmen Haeßner; Eberhardt Herdtweck; Martin Bohnenpoll; Oskar Nuyken; Fritz E. Kühn

Book ID
101835757
Publisher
John Wiley and Sons
Year
2004
Tongue
English
Weight
342 KB
Volume
10
Category
Article
ISSN
0947-6539

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Solvent influence on cationic copolymeri
Solvent influence on cationic copolymerization — Part II. Model calculations of the solvent influence on the cationic copolymerization of ethene and isobutene
✍ M. Bölke; P. Hallpap; G. Heublein; C. Weiss 📂 Article 📅 1988 🏛 Elsevier Science 🌐 English ⚖ 294 KB

Al~tract--The influence of solvent on cationic copolymerization, modelled by ethene/isobutene copolymerization, is investigated by theoretical methods. Solvent influence was simulated by a continuum model after gas phase calculations at the MINDO/3 level. Characteristic changes, caused by the transi

Alkyl Zinc Chlorides as New Initiators f
Alkyl Zinc Chlorides as New Initiators for the Polymerization and Copolymerization of Isobutene
✍ Antonio Guerrero; Kevin Kulbaba; Manfred Bochmann 📂 Article 📅 2008 🏛 John Wiley and Sons 🌐 English ⚖ 210 KB

## Abstract Mixtures of RZnCl and __t__BuCl (R = Et) initiate the polymerization of isobutene in the temperature range of (−35)—(+35) °C. The order of addition of the reagents is important for effective polymerization. Increasing the solubility of the zinc reagent (R = __n__‐octyl) and use of cumyl

Isobutene Polymerization and Copolymeriz
Isobutene Polymerization and Copolymerization with Isoprene Initiated by [Cp*TiMe2]+ in the Presence of a Novel Type of Weakly Coordinating Counteranion
✍ Calvin K. W. Tse; Kainthan Rajesh Kumar; Mark J. Drewitt; Michael C. Baird 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 127 KB

## Abstract Summary: The highly electrophilic borane B(C~6~F~5~)~3~ reacts with octadecanoic acid (__n__‐C~17~H~35~CO~2~H, stearic acid) to form 1:1 and 2:1 adducts [__n__‐C~17~H~35~CO~2~H][B(C~6~F~5~)~3~] and [__n__‐C~17~H~35~CO~2~H][B(C~6~F~5~)~3~]~2~. These adducts exhibit enhanced acidities, an