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Solvent influence on cationic copolymerization — part I. Derivation of a rule

✍ Scribed by M. Bölke; P. Hallpap; G. Heublein; C. Weiss

Publisher
Elsevier Science
Year
1988
Tongue
English
Weight
305 KB
Volume
24
Category
Article
ISSN
0014-3057

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✦ Synopsis

A~tract--The influence of solvent on cationic copolymerization is investigated by theoretical methods. Mathematical expressions of the quotients of reactivity ratios, r2/r t, of a copolymerization system are derived for the gas phase and solution. Considering some knowledge about solvation energies of charged and uncharged species in various solvents, a rule is derived describing the changes of r I and r 2: the value of r2/r ~ decreases on moving the copolymerization system to a more polar solvent.

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