Solvent induced conformational transformation of helical chains in new copper(II) coordination polymers
โ Scribed by Yan-Yan Yin; Xiao-Chang Cao; Peng Cheng; Jian-Gong Ma
- Book ID
- 118460360
- Publisher
- Elsevier Science
- Year
- 2012
- Tongue
- English
- Weight
- 568 KB
- Volume
- 24
- Category
- Article
- ISSN
- 1387-7003
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## Abstract A novel T4(1) water chain in a new Cu^II^ coordination polymer, {[Cu(C~4~H~6~N~2~)~2~(C~4~H~2~O~4~)] (H~2~O)~3~}__~n~__ (1, where C~4~H~6~N~2~ = 2โmethylimidazole, C~4~H~2~O~4~ = maleate), has been synthesized and structurally characterized by singleโcrystal Xโray diffraction. Thermogra
Refluxing of the red compound [Cu II L 1 ส(H 2 O)] (1) in acetone forms two new species: green Nะ-ethylenebis(3-ethoxysalicylaldimine)]. Whereas both 1 and 2 are converted into 3 upon heating, 3 is converted back into 1 when exposed to air. The structures of all three compounds were determined cryst