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Solvent impact on the aromaticity of benzene analogues: implicit versus explicit solvent approach

✍ Scribed by Piotr Cysewski; Beata Szefler; Katarzyna Kozłowska

Publisher
Springer-Verlag
Year
2009
Tongue
English
Weight
289 KB
Volume
15
Category
Article
ISSN
1610-2940

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Solvent versus substituent effects on the nitrogen NMR shielding of the nitro-group in substituted benzenes
✍ Michal Witanowski; Wanda Sicinska; Zenobia Biedrzycka; Graham A. Webb 📂 Article 📅 1993 🏛 John Wiley and Sons 🌐 English ⚖ 359 KB

## Abstract Intermolecular effects are shown to induce a variation of about 5 ppm in the nitrogen NMR shieldings of aromatic nitro groups. The latter turn out to be comparable to those exerted by substituents in nitrobenzene derivatives in solutions in a given solvent. Substituent effects on the NO