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Solvent-Free Thiolysis of Epoxides under Lithium Perchlorate Catalysis

✍ Scribed by Mohammad M. Mojtahedi; Hassan Abassi; M. Saeed Abaee; Bahareh Mohebali


Book ID
106213661
Publisher
Springer Vienna
Year
2006
Tongue
English
Weight
85 KB
Volume
137
Category
Article
ISSN
0026-9247

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Thiolysis of 1,2-epoxides by thiophenol
✍ Francesco Fringuelli; Ferdinando Pizzo; Simone Tortoioli; Luigi Vaccaro πŸ“‚ Article πŸ“… 2003 πŸ› Elsevier Science 🌐 French βš– 392 KB

Thiolysis of alkyl-and aryl-1,2-epoxides was investigated under solvent-free conditions in the presence of Lewis and BrΓΈnsted acid and base catalysts (InCl 3 , p-TsOH, n-Bu 3 P, K 2 CO 3 ). Five mol% of catalyst was sufficient and the best results were obtained by using InCl 3 and K 2 CO 3 . b-Hydro