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Solvent-Free Microwave Michael Addition Between EMME (I) and Various Nucleophiles.

โœ Scribed by Andre Loupy; Suk Jin Song; Seong Jin Cho; Dong Kyu Park; Tae Woo Kwon


Book ID
101977726
Publisher
John Wiley and Sons
Year
2005
Weight
22 KB
Volume
36
Category
Article
ISSN
0931-7597

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Silicon-based thiourea-mediated and micr
โœ Kamalakannan Prabakaran; Machindra Gund; Tae Kyu Kim; Euh Duck Jeong; Chae Young ๐Ÿ“‚ Article ๐Ÿ“… 2011 ๐Ÿ› Versita ๐ŸŒ English โš– 296 KB

## Abstract Silicon-based thiourea (SiliaBondยฎ Thiourea) (Si-THU), a heterogeneous catalyst, has been applied to the highly selective C-S bond formation via Michael addition of thiols to ฮฑ,ฮฒ-unsaturated carbonyl compounds under solvent-free conditions at 55โ€“60ยฐC. The thio-Michael addition products