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Solvent-Free Friedel–Crafts Cyclization with Trichloroacetic Anhydride

✍ Scribed by Andrews, Ben; Bullock, Kae; Condon, Shannon; Corona, John; Davis, Roman; Grimes, John; Hazelwood, Andrew; Tabet, Elie

Book ID
111896794
Publisher
Taylor and Francis Group
Year
2009
Tongue
English
Weight
329 KB
Volume
39
Category
Article
ISSN
0039-7911

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Solvent-free Friedel–Crafts acylation of
Solvent-free Friedel–Crafts acylation of aromatic compounds with carboxylic acids in the presence of trifluoroacetic anhydride and aluminum dodecatungstophosphate
✍ Habib Firouzabadi; Nasser Iranpoor; Farhad Nowrouzi 📂 Article 📅 2003 🏛 Elsevier Science 🌐 French ⚖ 103 KB

The stable and non-hygroscopic aluminum dodecatungstophosphate (AlPW 12 O 40 ), was found to be an effective catalyst (3 mol%) for the solvent-free Friedel-Crafts acylation of aromatic compounds with carboxylic acids in the presence of trifluoroacetic anhydride under mild reaction conditions.