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Solvent-free aziridination of α-nitroalkenes

✍ Scribed by Stefania Fioravanti; Lucio Pellacani; Sara Stabile; Paolo A. Tardella; Roberto Ballini

Book ID
104208597
Publisher
Elsevier Science
Year
1998
Tongue
French
Weight
392 KB
Volume
54
Category
Article
ISSN
0040-4020

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✦ Synopsis

NsOh'l-ICO2Et in the presence of CaO reacts without solvem with ct-nitmalkenes to give l-(etho~l)-2-nitrcaziridines (62-84%). A possible involvement of an aza-Michael route is ~of.,osed on the basis of rcgio-and ~cal reaction outcome, compared also with the results of thermolys/s of ethyl azidoformate on the same c~-nitroalkenes.

📜 SIMILAR VOLUMES

Aziridination of conjugated nitroalkenes
Aziridination of conjugated nitroalkenes
✍ Stefania Fioravanti; Lucio Pellacani; Sara Stabile; Paolo A Tardella; Roberto Ba 📂 Article 📅 1997 🏛 Elsevier Science 🌐 French ⚖ 103 KB

The recently proposed amination methodology based on solid bases induced decomposition of arenesulphonyloxycarbamates (ArSO3NHCO2Et) has been applied to ct-nitroalkenes, cc-Nitroaziridines have been obtained in high yields and purity, under mild conditions.