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Solvent-Free Aerobic Oxidation of Toluene over Metalloporphyrin/NHPI/CTAB: Synergy and Mechanism

โœ Scribed by Deng, Wei; Wan, Yan-ping; Jiang, Hui; Luo, Wei-Ping; Tan, Ze; Jiang, Qing; Guo, Can-Cheng

Book ID
121557211
Publisher
Springer US
Year
2013
Tongue
English
Weight
189 KB
Volume
144
Category
Article
ISSN
1011-372X

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Aerobic oxidation of p-xylene over metal
Aerobic oxidation of p-xylene over metalloporphyrin and cobalt acetate: Their synergy and mechanism
โœ Quan Jiang; Yang Xiao; Ze Tan; Qing-Hong Li; Can-Cheng Guo ๐Ÿ“‚ Article ๐Ÿ“… 2008 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 214 KB

The aerobic liquid-phase oxidation of p-xylene (PX) over metalloporphyrin and Co(OAc) 2 was studied, and the co-catalysis between metalloporphyrin and Co(OAc) 2 for the oxidation of PX was discovered for the first time. The results showed that both the PX conversion and terephthalic acid yield could