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Solvent effects upon the picosecond dynamics of proton transfer in 2-(N-methylanilino)acetophenone

โœ Scribed by Jens Dreyer; Kevin S. Peters

Book ID
112008857
Publisher
Wiley (John Wiley & Sons)
Year
1998
Tongue
English
Weight
404 KB
Volume
102
Category
Article
ISSN
0372-8323

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Picosecond dynamics of the twisted intra
Picosecond dynamics of the twisted intramolecular charge-transfer state formation of 4- (N,N-dimethylamino) benzonitrile (DMABN) in supercritical fluid solvent
โœ O. Kajimoto; T. Nayuki; T. Kobayashi ๐Ÿ“‚ Article ๐Ÿ“… 1993 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 325 KB

The rate of formation of the intramolecular charge-transfer state of 4-(N,N-dimethylamino)benzonitrile (DMABN) has been determined in supercritical CFsH using a fast single-photon counting technique. The rate constant increases rapidly with increasing CFIH density, indicating the importance of the p