𝔖 Bobbio Scriptorium
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Solvent effects on the unperturbed chain conformation of polysaccharides

✍ Scribed by Ranieri Urbani; Attilio Cesàro

Book ID
107846399
Publisher
Elsevier Science
Year
1991
Tongue
English
Weight
675 KB
Volume
32
Category
Article
ISSN
0032-3861

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Surprising Effects on the Conformational
Surprising Effects on the Conformational Entropy due to Nonrandom Distributions of Local Conformations Along Unperturbed Chains
✍ Wayne L. Mattice; Numan Waheed; Fatih Erguney 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 176 KB

## Abstract **Summary:** Nonrandomness in the distribution of rotational isomeric states along a flexible unperturbed chain reduces its conformational entropy. Pairwise interdependence of the bonds is a necessary, but not sufficient, condition for a significant reduction. The reduction in conformat