Solvent Effects on the Thioamide Rotational Barrier: An Experimental and Theoretical Study
β Scribed by Wiberg, Kenneth B.; Rush, Daniel J.
- Book ID
- 117994190
- Publisher
- American Chemical Society
- Year
- 2001
- Tongue
- English
- Weight
- 95 KB
- Volume
- 123
- Category
- Article
- ISSN
- 0002-7863
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
The results of systematic studies, using the CNDO/2-force model of Pulay and Torok, are presented for different methanol-water associations. The influence of the environment on the rotational harrier is discussed in detail. Molecular geometries, charge distributions and hvdration energies are also
## Abstract The EPR spectra of aminopropynyl and aminocyanomethyl radicals were recorded in a variety of solvents with different dielectric constants. For the former radical the spectra showed exchange broadening due to restricted rotation about the H~2~Nο£ΏCΛ bond. Arrhenius parameters for the bond