Solvent effects on the reaction rate and selectivity of synchronous heterogeneous hydrogenation of cyclohexene and acetone in ionic liquid/alcohols mixtures
✍ Scribed by Mohammad Khodadadi-Moghaddam; Aziz Habibi-Yangjeh; Mohamad Reza Gholami
- Publisher
- Elsevier Science
- Year
- 2009
- Tongue
- English
- Weight
- 351 KB
- Volume
- 306
- Category
- Article
- ISSN
- 1381-1169
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
## Abstract Kinetics of the reaction between 1‐chloro‐2,4‐dinitrobenzene and aniline was studied in mixtures of 1‐ethyl‐3‐methylimidazolium ethylsulfate ([EMIM][EtSO~4~]) with methanol, chloroform, and dimethylsulfoxide at 25°C. Single‐parameter correlations of log __k__~A~ versus normalized polari
## Abstract Fourier‐transform infrared and Raman spectroscopies have been used to investigate the role played by water on the structural organization of 1‐butyl‐3‐methyl‐imidazolium tetrafluoroborate and H~2~O mixtures, over a wide composition range at room temperature. Our measurements provide cle
## Abstract The second‐order rate coefficients for aromatic nucleophilic substitution reaction between 1‐chloro‐2,4‐dinitrobenzene and aniline have been measured in aqueous solutions of ethanol and methanol at 25°C. The plots of rate constants versus mole fraction of water show a maximum in all‐aqu
## Abstract Kinetics and solvent effects of the aquation of trans[Co(4‐(Etpy)~4~Cl~2~]^+^ have been studied in ethanol + water ranging from 0 to 60% (v/v) and urea + water of various solvent compositions up to 40% (w/w) of organic solvent. Thermodynamic activation parameters were computed and discu
Substitution reactions of some parasubstituted anilines with 2-chloro-5nitropyridine and 2-bromo-5-nitropyridine were carried out conductometrically in dimethylsulfoxide/acetonitrile mixtures. The correlation of second order rate constants with Hammett's substituent constants yields a fairly linear