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Solvent Effects on the Radiative Transitions of Singlet Oxygen

โœ Scribed by Ogilby, Peter R.


Book ID
127125559
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
178 KB
Volume
32
Category
Article
ISSN
0001-4842

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Mechanism of singlet oxygen interaction
โœ Alexander P. Darmanyan ๐Ÿ“‚ Article ๐Ÿ“… 1993 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 564 KB

The values of relative 0s ('A,) luminescence rate constant (kp ) in thirty-two solvents with ionization potentials IP = 8-l 1 eV are satisfactorily described by a linear dependence of log (kp /n 2, versus IP with a slope of -0.30 eV-i. Singlet oxygen acting as an electron acceptor forms a loose exci