## Abstract A PMR study of solvent effects on some __p__‐substituted phenyltin chlorides (substituents = CH~3~, (CH~3~)~3~C, CH~3~O) is reported. Co‐ordination of solvent molecules to the tin atom leads to an unusual low field shift of the __o__‐ring protons. The results for __p__‐tolytin trichlori
Solvent effects on the proton magnetic resonance spectra of thio- and dithio-oxamides
✍ Scribed by J. A. Lepoivre; H. O. Desseyn; F. C. Alderweireldt
- Publisher
- John Wiley and Sons
- Year
- 1974
- Tongue
- English
- Weight
- 426 KB
- Volume
- 6
- Category
- Article
- ISSN
- 0749-1581
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✦ Synopsis
Abstract
The chemical shifts of the N‐methyl signals for a number of thio‐oxamide and oxamide derivatives are unambiguously determined in the solvents chloroform, carbon tetrachloride, benzene, chlorobenzene, o‐dichlorobenzene and nitrobenzene. The ASIS effect is discussed. The temperature dependence of the absolute shift and of the relative shift differences of both methyl groups of the N,N‐dimethyl derivatives are studied.
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