𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Solvent effects on substitution reactions at complexes of the [Fe(CN)5L]3-type in binary aqueous mixtures

✍ Scribed by Maria Luisa Moyá; Antonio Barrios; Maria del Mar Graciani; Rafael Jiménez; Ernestina Muñoz; Francisco Sánchez; John Burgess

Publisher
Springer
Year
1991
Tongue
English
Weight
446 KB
Volume
16
Category
Article
ISSN
0340-4285

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Kinetics of aquation of Co(III) complex
Kinetics of aquation of Co(III) complex in binary aqueous mixtures and effect of multiparameters of the solvent on the reaction rate
✍ Gehan M. El-Subruiti; Magda F. Fathalla; Yasser R. El-Marassi 📂 Article 📅 2011 🏛 John Wiley and Sons 🌐 English ⚖ 105 KB 👁 1 views

## Abstract Kinetics and solvent effects of the aquation of trans[Co(4‐(Etpy)~4~Cl~2~]^+^ have been studied in ethanol + water ranging from 0 to 60% (v/v) and urea + water of various solvent compositions up to 40% (w/w) of organic solvent. Thermodynamic activation parameters were computed and discu

Ionic strength effects in binary aqueous
Ionic strength effects in binary aqueous mixtures: Study of the reaction between Co(en)2(2-pzCO2)2+ and Fe(CN)5H2O3−
✍ Amalia Rodríguez; Pilar Pérez-tejeda; Rafael Jiménez; Francisco Sánchez; Pilar L 📂 Article 📅 1995 🏛 John Wiley and Sons 🌐 English ⚖ 498 KB 👁 2 views

The reaction between Co(en)2(2-pzCO~)~' (bis-ethylenediamine (2-pyrazinecarboxylato)cobalt(III)) and Fe(CN)5H203-(aquopentacyanoferrate(I1)) to form the binuclear complex [(en)aCo( pL-pzC02)Fe(CN51-has been studied in several isodielectric binary mixtures at 298.2 K (cosolvents: methanol, ethanol, t

Micellar effects on a ligand substitutio
Micellar effects on a ligand substitution reaction: Kinetics of the formation of [Fe(CN)5(μ-pz)Ru(NH3)5]−, from [Fe(CN)5H2O]3− and [Ru(NH3)5pz]2+, in the presence of anionic micelles
✍ Rafael Jiménez; Elena Bueno; Israel Cano; Elizabeth Corbacho; M. Eugenia Fernánd 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 96 KB 👁 2 views

## Abstract The kinetics of substitution of H~2~O by Ru(NH~3~)~5~pz^2+^ (pz = pyrazine) in Fe(CN)~5~H~2~O^3−^ have been studied in micellar aqueous solutions of sodium dodecylsulfate (SDS). Experimental results are discussed by using an approach based on the transition‐state theory. This approach i