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Solvent Effects on Ion-Pair Distribution and Dimerization of Tetraalkylammonium Salts

✍ Scribed by Kiyoshi Sawada; Eiji Takahashi; Tomokazu Horie; Keiichi Satoh

Book ID: 106214901
Publisher: Springer Vienna
Year: 2001
Tongue: English
Weight: 170 KB
Volume: 132
Category: Article
ISSN: 0026-9247
DOI: 10.1007/s007060170026

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## Abstract Salt effects on the reactions [Fe(CN)~6~]^4−^ + S~2~O^=^~8~ and [Ru(NH~3~)~5~py]^2+^ + S~2~O have been studied in media of different dielectric constants constituted by mixtures of water with organic cosolvents. It is known that salt and solvent effects are coupled and, consequently, ca