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Solvent Effects on Hydrogen Abstraction Reactions from Lactones with Antioxidant Properties

✍ Scribed by Aspée, Alexis; Scaiano, J. C.; Aliaga, Carolina; Stuart, David R.


Book ID
111691647
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
80 KB
Volume
7
Category
Article
ISSN
1523-7060

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Hydrogen abstraction from organosilicon
✍ J. A. Kerr; D. M. Timlin 📂 Article 📅 1971 🏛 John Wiley and Sons 🌐 English ⚖ 634 KB

The photolysis of 1,1,3,3-tetrafluoroacetone has been reinvestigated as a source of CHFz radicals at temperatures up to 578'K, and the following rate constant ratio was determined for the reactions (8) (7) 2CHF2 -+ CHFzCHFz\* CHFz + CHFzCOCHFz -+ CHzFz + CF~COCHFZ log (k~/k~1'2)(mole-1'zcc1'2sec-1'2