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Solvent Effects in the Reaction of p-Substituted α-Chlorotoluenes with Thiosulfate

✍ Scribed by Fuchs, Richard

Book ID: 120385617
Publisher: American Chemical Society
Year: 1957
Tongue: English
Weight: 363 KB
Volume: 79
Category: Article
ISSN: 0002-7863
DOI: 10.1021/ja01581a047

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## Abstract Pseudo‐first‐order rate constants have been determined for the nucleophilic substitution reactions of __p__‐nitrophenyl acetate with __p__‐chlorophenoxide (4‐ClC~6~H~4~O^−^) and __N__‐phenylbenzohydroxamate (C~6~H~5~CON(C~6~H~5~)O^−^) ions in phosphate buffer (pH 7.7) at 27°C. The effec