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Solvent effects in nuclear magnetic resonance spectroscopy solvent shifts induced by benzene in amines

✍ Scribed by D.J. Barraclough; P.W. Hickmott; O. Meth-Cohn

Publisher: Elsevier Science
Year: 1967
Tongue: French
Weight: 185 KB
Volume: 8
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)73016-4

No coin nor oath required. For personal study only.

✦ Synopsis

Wnivereity of Salford, galford, Lance.) (Received in UK 27 July 1967)

It is now ~011 known1 that benzene ooueee coneiderable Bolvent shifte of pi-&m reacnauoea (A-TC6D6 -fCCla) with respect to IYI 'inert' solvent in WWD spectra. The origin of suoh solvent shifts ie believed to lie in the ability of ben5ene to aolvate an araaatic or aliphatic eolute moleoule at electron defioient sites of looal dipolerr in a eteroepecific manner, the ehifta arirring due to the magnetic auia+ot.ropg of the benzene ring.

It has been suggested by William6 and co-workers1 that nonplenar collieion ocqplexes are formed, in which the JT-electron syrtem of beneene interacts in such a ra(y that the benzene

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