Solvent Effects in NMR Spectroscopy. The Geometry of Solute/Solvent Collision Complexes

✍ Scribed by T. Ledaal

• Publisher: Elsevier Science
• Year: 1968
• Tongue: French
• Weight: 351 KB
• Volume: 9
• Category: Article
• ISSN: 0040-4039
• DOI: 10.1016/s0040-4039(01)99029-x

✦ Synopsis

The specific shielding effect in IjPIFi shown by aromatic solvents on polar solutes is experimentally well established. During the ten years since its discovery (1,2), many workers have investigated this effect and stereochemical aspects of it. (Papers containing many references:

(3,4), more re- cent works:

(5-24)). It is felt, however, that this effect and its potential applications by no means has attained the attention it deserves. One reason for this may be the lack of a generally