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Solvent effects in deamination reactions

โœ Scribed by Klaus Banert; Michael Bunse; Theodor Engbert; Karl-Rudolf Gassen; Apriana W. Kurnianto; Wolfgang Kirmse

Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
743 KB
Volume
105
Category
Article
ISSN
0165-0513

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Norbornanediazonium ions / endo Selectivity / Norpinyl cations / Cyclopropylcarbinyl cations Nitrous acid deamination of spiro[bicyclo[2.2.l]heptane-7,1'cyclopropan]-endo-2-amine (13) affords 74% of the analogous endo alcohol 24-OH and 26% of the rearranged exo alcohol 25-OH. The exceptional prefere