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Solvent effect on the proton-transfer equilibria and thermodynamic data of the hydrogen bond in a Mannich base

✍ Scribed by Rospenk, Maria; Fritsch, Johannes; Zundel, Georg


Book ID
120273538
Publisher
American Chemical Society
Year
1984
Tongue
English
Weight
358 KB
Volume
88
Category
Article
ISSN
0022-3654

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Dimerization and solvent-assisted proton
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Using low-temperature UV, 1 H and 15 N NMR spectroscopy, we studied the easily polarizable bond of the labeled Mannich base[ 15 N] 2-(N,Ndiethylaminomethyl)-3,4,6-trichlorophenol (Cl 3 MB) dissolved in dichloromethane and in a 2 : 1 mixture of CDF 3 and CDClF 2 . Whereas at high temperature the mol