## Abstract In this paper it is shown that the charge transfer kinetics of the oxidation of sodium dithionite at a gold electrode in alkaline solution can be increased by modifying this electrode with cobalt(II)tetrasulfonated phthalocyanine, sodium salt (CoTSPc) or 5,10,15,20βtetrakisβ(4βsulfonato
β¦ LIBER β¦
Solvent Effect on Protonation Constants of 5, 10, 15, 20-Tetrakis(4-sulfonatophenyl)porphyrin in Different Aqueous Solutions of Methanol and Ethanol
β Scribed by Ali Farjtabar; Farrokh Gharib
- Publisher
- Springer US
- Year
- 2010
- Tongue
- English
- Weight
- 452 KB
- Volume
- 39
- Category
- Article
- ISSN
- 0095-9782
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High-valent oxo-iron(IV) species are commonly proposed as the key intermediates in the catalytic mechanisms of iron enzymes. Water-soluble iron(III) tetrakis-5,10,15,20-(N-methyl-4-pyridyl)porphyrin (Fe(III)TMPyP) has been used as a model of heme-enzyme to catalyse the hydrogen peroxide (H 2 O 2 ) o