Solvent effect on photophysics of the molecular forms of rhodamine B. Solvation models and spectroscopic parameters
β Scribed by I.Lopez Arbeloa; K.K. Rohatgi-Mukherjee
- Publisher
- Elsevier Science
- Year
- 1986
- Tongue
- English
- Weight
- 635 KB
- Volume
- 128
- Category
- Article
- ISSN
- 0009-2614
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β¦ Synopsis
Photophysics and spectral characteristics of the zwitterionic and cationic forms of rhodamine B have been studied in a number of protic and aprotic solvents with different solvation properties. The results have been discussed on the basis of the molecular structures of the dye, role of carboxyphenyl group and specific solute-solvent interactions.
π SIMILAR VOLUMES
A new microscopic model for the quantitative interpretation of solvent effects on molecular eiectrooic spectxa is proposed. The interaction ener& is caicuIated between the solute molecule and a camplet. shell of surrounding solvent nolecutes. The equilibrium configuration is obtained by a procedur
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