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Solvent effect on electron transfer reactions. The system Co(phen)33+-ferrocene in water-alcohol mixtures

✍ Scribed by Ezio Pelizzetti; Roberto Giordano


Book ID
115976506
Publisher
Elsevier Science
Year
1981
Weight
254 KB
Volume
43
Category
Article
ISSN
0022-1902

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The electrode reaction of the C~(en):+'~+ couple on mercury electrodes in water-acetonitrile (AN), water-DMSO and water-hexamethylphosphortriamide (HMPT) mixed solvents has been investigated. The differences between Gibbs energies of transfer of the Co(en):+ and Co(en)$+ ions from water to mixtures