✦ LIBER ✦
Solvent effect on cleavage rate constants of radical anions. Contribution from non-equilibrium solvent polarization
✍ Scribed by Jan S. Jaworski
- Publisher
- Elsevier Science
- Year
- 1999
- Tongue
- French
- Weight
- 140 KB
- Volume
- 40
- Category
- Article
- ISSN
- 0040-4039
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✦ Synopsis
Solvent effects on the bond cleavage in three aromatic radical anions are described in an uniform way applying the Sav6.ant model: the intrinsic rate constants, obtained from experimental data measured recently by Jensen and Daasbjerg after the substraction of a thermodynamic contribution to the activation barrier, depend linearly on the solvent Pekar factor. Calculations of the solvent reorganization energy support the correlations found.