𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Solvent dipolarity/polarizability (SPP) of alcoholic solvents

✍ Scribed by Catalán, Javier ;López, Vicenta ;Pérez, Pilar

Book ID
102367348
Publisher
John Wiley and Sons
Year
1995
Tongue
English
Weight
302 KB
Volume
1995
Category
Article
ISSN
0947-3440

No coin nor oath required. For personal study only.

✦ Synopsis

Polarity scale / Solvatochromism / Alcoholic solvents The positive solvatochromism exhibited by 2-(dimethylamino)-7-nitrofluorene (DMANF) and 2-fluoro-?-nitrofluorene (FNF) was used to determine the solvent dipolarity/polarizability (SPP) of 29 saturated aliphatic alcohols, four unsaturated alcohols, an aromatic alcohol, a triol, and water. The SPP values for the alcohols lie at the top of the SPP solvent polarity scale. The SPP values for n-alkanols decreases with increasing chain length, in contrast to the behavior of n-alkanes. On the other hand, the polarity of n-alkanols, like that of n-alkanes, increases on cyclization. The polarity of m-cresol (1.0) and of 1,1,1,3,3,3-hexafluoro-2-propanol (1.007') places these solvents at the top of the SPP scale.

📜 SIMILAR VOLUMES

Ionic Interactions in a Polarizable Dipo
Ionic Interactions in a Polarizable Dipolar Hard-Sphere Solvent
✍ Dr. Hartmut Krienke; Gisbert Weigl 📂 Article 📅 1988 🏛 John Wiley and Sons 🌐 English ⚖ 829 KB

A b s t r a c t . Potentials of mean forces of ions in infinitely diluted solutions are calculated b y means of a general virial expansion for systems with short and long range interactions. The screened potentials are calculated by the MSA-approximation for the chain sum in the mixture model. ## I