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Solvent dependent stereochemistry of cyanide anation of some chromium(III) complexes

โœ Scribed by Pietro Riccieri; Edoardo Zinato

Book ID
104138651
Publisher
Elsevier Science
Year
1980
Tongue
English
Weight
176 KB
Volume
40
Category
Article
ISSN
0020-1693

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โœฆ Synopsis

Posters Complex M.p. colour &ff.) ReCIz(Me-sal)(PMezPh)z 183 red 2.1 ReBrz(Me-sal)(PMezPh)z 204 red 2.0 ReClz(Ph-sal)(PMezPh)z 207 red 2.1 ReBrz(Ph-sal)(PMezPh)z 190 red 2.0 Rez & (salzen)(PMezPh)4 199 red 2.0 cis-ReOClz(Mesal)PMe2Ph 182 light green diam. truns-ReOC12(Me-sal)PMe2Ph 179 dark green diam. cis-ReOC12(Phsal)PMe2Ph 229 bright green diam. &ReOClz(oxine)PMe2Ph 274 dark green diam. truns-ReOC12(oxine)PMe2Ph 258 dark green diam . RezOzC14(sal2en)(PMe2Ph)2

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The intensity of the narrow-line luminescence of crvstalline 2Cr(en)2C12\*KC1.6H20 has been found to pass through a maximum at ZOOOK and a new broad emission band appears below 140ยฐ. The emission properties of the Cr(en)$' . Ion are strongly dependent on its environment.