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Solvent-Dependent Decarboxylation of 1,3-Dimethylimdazolium-2-Carboxylate

โœ Scribed by Denning, Derek M.; Falvey, Daniel E.


Book ID
123609235
Publisher
American Chemical Society
Year
2014
Tongue
English
Weight
379 KB
Volume
79
Category
Article
ISSN
0022-3263

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โœ D.S. Kemp; J. Reczek; F. Vellaccio ๐Ÿ“‚ Article ๐Ÿ“… 1978 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 113 KB

Previously, we have shown that the benzisoxazole-3-carboxyTates, b, undergo an intermediateless conversion to carbon dioxide and g-cyanophenolate, 5, that is subject to very large solvent rate accelerations. 2 Recently, Klotz and coworkers have demonstrated a pronounced catalysis by aqueous solution