The thermodynamic and kinetic properties of trans-3,4,5, 6-tetramethyl-9,10-dihydro-9,10-dihydroxyphenanthrene (4) and its derivatives were studied. The equilibrium ratios of two the possible conformers (4eq, 4ax) were measured in various solvents, where consistently the equatorial conformers proved
โฆ LIBER โฆ
Solvent dependence of the conformation and chiroptical properties of trans-9,10-dihydroxy-9,10-dihydrophenanthrene and its monoglucuronides
โ Scribed by Cobb, Diane I.; Lewis, Deborah A.; Armstrong, Richard N.
- Book ID
- 126423375
- Publisher
- American Chemical Society
- Year
- 1983
- Tongue
- English
- Weight
- 409 KB
- Volume
- 48
- Category
- Article
- ISSN
- 0022-3263
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## Abstract The compound __trans__โ1,5โdichloroโ9,10โdiethynylโ9,10โdihydroanthraceneโ9,10โdiol (DDDA) has an inversion center as the only molecular symmetry element and yet does not occupy an inversion center in the centrosymmetric space group that it adopts in the crystal structure. The reason fo
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