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Solvent dependence of singlet oxygen / substrate interactions in ene-reactions, (4+2)- and (2+2)-cycloaddition reactions

✍ Scribed by Klaus Gollnick; Axel Griesbeck

Publisher: Elsevier Science
Year: 1984
Tongue: French
Weight: 244 KB
Volume: 25
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)80010-1

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✦ Synopsis

In ref. 8, B-values were determined by using polymer-bound RB (Sensitox). The insoluble sensitizer did not allow to determine R by extrapolation to zero sensitizer concentration thus leading to too small kr-values (especially in CC14) and, consequently, to a too large dipole moment for the transition state of 5.6 D.

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