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Solvent assistance in the solvolysis of secondary substrates. III. A method for estimating the magnitude of solvent assistance

✍ Scribed by Schleyer, Paul von R.; Fry, J. L.; Lam, L. K. M.; Lancelot, Charles J.

Book ID: 121507626
Publisher: American Chemical Society
Year: 1970
Tongue: English
Weight: 403 KB
Volume: 92
Category: Article
ISSN: 0002-7863
DOI: 10.1021/ja00711a055

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📜 SIMILAR VOLUMES

Solvent assistance in the solvolysis of

Solvent assistance in the solvolysis of secondary substrates. I. The 2-adamantyl system, a standard for limiting solvolysis in a secondary substrate

✍ Fry, James L.; Lancelot, Charles J.; Lam, Leo K. M.; Harris, J. Milton.; Bingham 📂 Article 📅 1970 🏛 American Chemical Society 🌐 English ⚖ 425 KB

Solvent assistance in the solvolysis of

Solvent assistance in the solvolysis of secondary substrates. Use of added azide ion as a mechanistic probe

✍ Harris, Joe Milton.; Raber, Douglas J.; Hall, Robert E.; Schleyer, Paul V. R. 📂 Article 📅 1970 🏛 American Chemical Society 🌐 English ⚖ 411 KB

Solvent assistance in the solvolysis of

Solvent assistance in the solvolysis of secondary substrates. IV. Solvolytic behavior of the di-tert-butylcarbionyl system

✍ Liggero, Samuel H.; Harper, Jon J.; Schleyer, Paul v. R.; Krapcho, A. Paul.; Hor 📂 Article 📅 1970 🏛 American Chemical Society 🌐 English ⚖ 349 KB

An estimate of steric influence on nucle

An estimate of steric influence on nucleophilic solvent assistance in secondary solvolysis.

✍ Addy Pross; Rodi Koren 📂 Article 📅 1974 🏛 Elsevier Science 🌐 French ⚖ 193 KB

Nordlander' has recently evaluated expression (i) for a number of solvents, where k pinOTs and kg adOTs are the solvolytic rate constants for pinacolyl tosylate and Z-adamantyl tosylate respectively in those solvents and interpreted the data in terms of ion-pair return in the solvolysis of 2-adamant

Solvent assistance in the solvolysis of

Solvent assistance in the solvolysis of secondary substrates. II. The .alpha.-methyl-hydrogen rate ratio for the 2-adamentyl system

✍ Fry, James L.; Harris, J. Milton.; Bingham, Richard C.; Schleyer, Paul von R. 📂 Article 📅 1970 🏛 American Chemical Society 🌐 English ⚖ 431 KB

Essentially solvent-independent rates of

Essentially solvent-independent rates of solvolysis of the 1-adamantyldimethylsulfonium ion. Implications regarding nucleophilic assistance in solvolyses of tert-butyl derivatives and the NKL solvent nucleophilicity scale

✍ Kevill, Dennis N.; Anderson, Steven W. 📂 Article 📅 1986 🏛 American Chemical Society 🌐 English ⚖ 991 KB