Solvent and temperature dependent circular dichroism of (+)-(5R)-spiro[4·4]-nonan-1,6-dione
✍ Scribed by David A. Lightner; Gary D. Christiansen; John L. Melquist
- Book ID
- 108384450
- Publisher
- Elsevier Science
- Year
- 1972
- Tongue
- French
- Weight
- 200 KB
- Volume
- 13
- Category
- Article
- ISSN
- 0040-4039
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A highly stereoselective and enantioselective reduction of racemic spiro[4.4]nonane-1,6-dione catalyzed by an oxazaborolidine reagent is described. The asymmetric reduction of the racemic spirodiketones resulted in enantiomerically pure spirodiols which are useful chiral auxiliaries and also key int