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Solvent and Structural Effects on the Activation Parameters of the Reaction of Carboxylic Acids with Diazodiphenylmethane

✍ Scribed by Nikolić, J. B.; Ušćumlić, G. S.


Book ID
120647616
Publisher
John Wiley and Sons
Year
2013
Tongue
English
Weight
170 KB
Volume
45
Category
Article
ISSN
0538-8066

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📜 SIMILAR VOLUMES


Solvent and structural effects on the ki
✍ J. B. Nikolić; G. S. Ušćumlić; V. V. Krstić 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 102 KB

## Abstract The rate constants for the reaction of different cycloalkenylcarboxylic, cycloalkenylacetic acids, and phenylacetic acid with diazodiphenylmethane were determined in 12 aprotic solvents at 30°C. In order to explain the kinetic results through solvent effects, the second‐order rate const

Solvent and structural effects on the ki
✍ J. B. Nikolić; G. S. Ušćumlić; I. O. Juranić 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 214 KB

## Abstract The rate constants for the reaction of 2‐methyl‐cyclohex‐1‐enylcarboxylic, 2‐phenylcyclohex‐1‐enylcarboxylic, and 2‐methylbenzoic and 2‐phenylbenzoic acids with diazodiphenyl‐methane were determined in 14 various solvents at 30°C. To explain the kinetic results through solvent effects,

A new interpretation of the kinetics of
✍ N.B. Chapman; A. Ehsan; J. Shorter; K.J. Toyne 📂 Article 📅 1968 🏛 Elsevier Science 🌐 French ⚖ 289 KB

The reaction between diasodiphenylmethane and carboxylic acids in ethanol or other alcohols as solvent has been much studied (see references 2 to 1Y in reference (1) of this note and references 2 to 8) and the main features of the mechanism have now been established (1,2).