## Abstract The rate constants for the reaction of different cycloalkenylcarboxylic, cycloalkenylacetic acids, and phenylacetic acid with diazodiphenylmethane were determined in 12 aprotic solvents at 30°C. In order to explain the kinetic results through solvent effects, the second‐order rate const
Solvent and Structural Effects on the Activation Parameters of the Reaction of Carboxylic Acids with Diazodiphenylmethane
✍ Scribed by Nikolić, J. B.; Ušćumlić, G. S.
- Book ID
- 120647616
- Publisher
- John Wiley and Sons
- Year
- 2013
- Tongue
- English
- Weight
- 170 KB
- Volume
- 45
- Category
- Article
- ISSN
- 0538-8066
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## Abstract The rate constants for the reaction of 2‐methyl‐cyclohex‐1‐enylcarboxylic, 2‐phenylcyclohex‐1‐enylcarboxylic, and 2‐methylbenzoic and 2‐phenylbenzoic acids with diazodiphenyl‐methane were determined in 14 various solvents at 30°C. To explain the kinetic results through solvent effects,
The reaction between diasodiphenylmethane and carboxylic acids in ethanol or other alcohols as solvent has been much studied (see references 2 to 1Y in reference (1) of this note and references 2 to 8) and the main features of the mechanism have now been established (1,2).