Solvent and Base Effects on the Mechanism of the E2 Reaction
β Scribed by Froemsdorf, D. H.; McCain, M. E.; Wilkison, W. W.
- Book ID
- 126160086
- Publisher
- American Chemical Society
- Year
- 1965
- Tongue
- English
- Weight
- 276 KB
- Volume
- 87
- Category
- Article
- ISSN
- 0002-7863
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π SIMILAR VOLUMES
In a recent publication2 the mechanism of the reaction of i-arylethyltrimethylammonium ions with ethoxide ion in ethanol at 70Β° was shown to be E2. The transition state for this process involved extensive proton transfer to base as exhibited by the observed trend in hydrogendeuterium isotope effects
AbstractPSome interesting results of recent experimental studhes on electrode potentials, kinetic parameters and reaction mechamsms of electrode reactions in various organic and mixed solvents are presented. The relationship which was revealed between the R, value of the modified Born equation and d