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Solvent and additive effects on the polymerization of phenylacetylenes

✍ Scribed by Kan-ichi Hasegawa

Publisher
Elsevier Science
Year
1977
Tongue
English
Weight
740 KB
Volume
13
Category
Article
ISSN
0014-3057

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Effects of ortho-substituents on the liv
Effects of ortho-substituents on the living polymerization of phenylacetylenes by MoOCl4-based catalysts
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Polymerization of phenylacetylenes (PAS) having various ortho-substituents were examined by using MoOCI,-n-Bu,Sn-EtOH (mole ratio 1 : 1 : 1) as catalyst. Phenylacetylenes with no or sterically small ortho-substituents did not polymerize in a living fashion. On the other hand, in the polymerization o

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