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Solvatochromic hydrogen bond donor acidity of cyclodextrins and reversed-phase liquid chromatographic retention of small molecules on a β-cyclodextrin-bonded silica stationary phase

✍ Scribed by Jung Hag Park; Myung Duk Jang; Moon Ju Shin


Publisher
Elsevier Science
Year
1992
Tongue
English
Weight
692 KB
Volume
595
Category
Article
ISSN
1873-3778

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A cyclomaltoheptaose (J3-cyclodextrin) bonded-phase HPLC column was used for the first time to separate acidic oligosaccharides. Oligogalacturonic acids up to a degree of polymerization (dp) of 7 were separated with a 50:50 acetonitrile-sodium phosphate-buffered (pH 5) mobile phase and up to dp 17 w