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Solvation of Uranyl(II) and Europium(III) Cations and Their Chloro Complexes in a Room-Temperature Ionic Liquid. A Theoretical Study of the Effect of Solvent “Humidity”

✍ Scribed by Chaumont, Alain; Wipff, Georges

Book ID
111867024
Publisher
American Chemical Society
Year
2004
Tongue
English
Weight
778 KB
Volume
43
Category
Article
ISSN
0020-1669

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Solvation of Uranyl(II), Europium(III) a
Solvation of Uranyl(II), Europium(III) and Europium(II) Cations in “Basic” Room-Temperature Ionic Liquids: A Theoretical Study
✍ Alain Chaumont; Georges Wipff 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 412 KB 👁 1 views

## Abstract We report a molecular dynamics study of the solvation of UO~2~^2+^, Eu^3+^ and Eu^2+^ ions in two “basic” (Lewis acidity) room‐temperature ionic liquids (IL) composed of the 1‐ethyl‐3‐methylimidazolium cation (EMI^+^) and a mixture of AlCl~4~^−^ and Cl^−^ anions, in which the Cl^−^/AlCl