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Solvation of monovalent anions in acetonitrile and N,N-dimethylformamide: Parameterization of the IEF-PCM model

✍ Scribed by Elvis S. Böes; Paolo R. Livotto; Hubert Stassen


Book ID
108088855
Publisher
Elsevier Science
Year
2006
Tongue
English
Weight
514 KB
Volume
331
Category
Article
ISSN
0301-0104

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✍ J. Szafko; W. Feist; B. Pabin-Szafko 📂 Article 📅 1996 🏛 John Wiley and Sons 🌐 English ⚖ 528 KB

The thermal decomposition rate constant of AIBN ( k d ) in N,N-dimethylformamide (DMF)/ acrylonitrile (AN) mixtures of various compositions at 60°C is studied. The k d value is (6.45 +. 0.3) X min-' for pure acrylonitrile. The k d values of DMF/AN mixtures were found to be dependent on the mixture