Kinetic solvation steric effect at the t
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Yasuhiro Umebayashi; Nobuyuki Shigeta; Yue Zhang; Morito Komiya; Yu-ichi Murakam
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Article
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2005
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Elsevier Science
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English
β 489 KB
The rate of the solvent substitution reaction, CoCl 3 S Γ +Cl Γ YCoCl 4 2Γ +S (S-solvent) has been studied by means of stopped flow spectrophotometry in dimethyl sulfoxide (DMSO) and N,N-dimethylformamide (DMF), and the rate constant k f , and the activation enthalpy D f H p and entropy D f S p have