Solvation of ions in binary solvents - experimental and MD simulation studies
β Scribed by Ewa Hawlicka; Dorota Swiatla-Wojcik
- Publisher
- Elsevier Science
- Year
- 1998
- Tongue
- English
- Weight
- 602 KB
- Volume
- 78
- Category
- Article
- ISSN
- 0167-7322
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π SIMILAR VOLUMES
Abshact-In order to throw light on ion-solvent interactions, the salvation numbers of electrolytes in different mixed solvents (methanol + water and ethanol + water mixtures) have been determined using ultrasonic interferometer. The anomalies in the salvation number of cations (in aqueous solutions)
A microscopic theory is described for the ion solvation dynamics in binary dipolar liquids. The theory is self-contained and properly includes inertial and non-Markovian effects which are extremely important in the fast initial phase of the relaxation. The theory also includes diffusional effects im